I have no idea how particular it is to phrase it that way, but it isn't confused.
(what it comes down to is that "an" is an indefinite article and always modifies a noun and km/ss is described by the verb acceleration. Yay English.)
Delta-v is common in orbital mechanics, which is often referred as "an acceleration".
I have no idea how particular it is to phrase it that way, but it isn't confused.